Parallel Polar Dimers in the Columnar Self?Assembly of Umbrella?Shaped Subphthalocyanine Mesogens

نویسندگان

چکیده

The self-assembly of umbrella-shaped mesogens is explored with subphthalocyanine cores and oligo(thienyl) arms different lengths in the light their application as light-harvesting photoconducting materials. While shortest arm derivatives self-assemble a conventional columnar phase single mesogen repeating unit, more extended generate dimers that pile up into liquid crystalline columns. In contrast to antiparallel arrangement known from crystals, present align parallel polar phases confirmed by X-ray scattering, experimental densities, dielectric spectroscopy, second harmonic generation, alignment, conductivity studies. UV–vis fluorescence spectroscopies reveal broad absorption visible range only weak emission Q-band. Thus, these light-collecting molecules forming strongly mesophases are attractive for area photoconductive

برای دانلود باید عضویت طلایی داشته باشید

برای دانلود متن کامل این مقاله و بیش از 32 میلیون مقاله دیگر ابتدا ثبت نام کنید

اگر عضو سایت هستید لطفا وارد حساب کاربری خود شوید

منابع مشابه

determination of maximal singularity free zones in the workspace of parallel manipulator

due to the limiting workspace of parallel manipulator and regarding to finding the trajectory planning of singularity free at workspace is difficult, so finding a best solution that can develop a technique to determine the singularity-free zones in the workspace of parallel manipulators is highly important. in this thesis a simple and new technique are presented to determine the maximal singula...

15 صفحه اول

Helical buckling in columnar assemblies of soft discotic mesogens.

We investigate the emergence of chiral meso-structures in one-dimensional fluids consisting of stacked discotic particles and demonstrate that helical undulations are generated spontaneously from internal elastic stresses. The stability of these helical conformations arises from an interplay between long-ranged soft repulsions and nanopore confinement which is naturally present in columnar liqu...

متن کامل

Bilayers in nanoparticle-doped polar mesogens.

Structures of the mesophases of five members of the 4-n-alkyl-4'-cyanobiphenyl homologous series (4-n-butyl-4'-cyanobiphenyl to 4-n-octyl-4'-cyanobiphenyl) doped with milled BaTiO_{3} nanoparticles were investigated by x-ray scattering. Clear solutions of each of the 4-n-alkyl-4'-cyanobiphenyls were first prepared in n-heptane and then doped with an n-heptane/nanoparticle dispersion, which led ...

متن کامل

Trigonal columnar self-assembly of bent phasmid mesogens.

Three compounds with a bent rod-like aromatic core and with three alkoxy chains at each end were synthesised by click reaction. The compounds form a columnar liquid crystal phase with non-centrosymmetric trigonal p31m symmetry, the columns having a 3-arm star-like cross-section.

متن کامل

ذخیره در منابع من


  با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید

ژورنال

عنوان ژورنال: Advanced Functional Materials

سال: 2021

ISSN: ['1616-301X', '1616-3028']

DOI: https://doi.org/10.1002/adfm.202104217